According to Vice, Libras tend to get easily annoyed when a date tries to impress them by showing off factors like their career or their income. This means that unless you want your date to end up annoying you, it's best to steer clear of questions about success. Instead, opt to keep things more light-hearted and fun.
According to Bustle, Libras are ruled by Venus, which means that most Libras are romantics. Usually, Libras have a good sense of balance, hence the scale symbol, and a good sense of beauty. Libras are also usually artistic and gain pleasure from aesthetically pleasing things. A good question to ask on a first date could be "What's one place that you have visited and thought was the most beautiful place you have seen?" This will tell you more about the person, their experiences, and whether they are a good fit for your star sign.
As per Bustle, you will probably have a better conversation if you tailor the questions that you ask to your star sign and their star sign. Bearing that in mind, the ultimate first question could be "What is your star sign?"
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